Title : ( Synthesis and Spectroscopic Characterization of Mixed Diamidophosphoric Acid Esters: X-Ray Crystal Structure of [(CH3)2N]-[p-H3C-C6H4-O]P(O)X (X = NHC(CH3)3 and p-H3C-C6H4-NH) )
Authors: Saied Ghadimi , Mehrdad Pourayoubi , Ali Asghar Ebrahimi Valmoozi ,
Full TextAbstract
Mixed diamidophosphoric acid esters [(CH3)2N][p-H3C-C6H4-O]P(O)X, where X = NH(CH3) (1), NHCH(CH3)2 (2), NHC(CH3)3 (3) and p-H3C-C6H4-NH (4) were synthesized and characterized by 31P, 31P{1H}, 13C, 1H NMR, and IR spectroscopy and mass spectrometry, and single crystal X-ray diffraction analysis for the compounds 3 and 4. Compound 3 crystallizes in the monoclinic, space group P21/c with unit cell parameters a = 9.006(3), b = 16.286(5), c = 10.319(3) A° , β = 99.633(6)◦, V = 1492.2(8) °A3, Z = 4. The final R value is 0.0622 for 2074 reflections [I ≥ 2σ (I)]. Compound 4 crystallizes in the orthorhombic, space group Pna21 with unit cell parameters a = 7.0459(14), b = 20.934(4), c = 10.436(2) ° A, V = 1539.3(5) °A3, Z = 4. The final R value is 0.0530 for 3025 reflections [I ≥ 2σ (I)].
Keywords
, Mixed Diamidophosphoric Acid Ester, Spectroscopic Characterization, X-Ray Crystal Structure
@article{paperid:1011317,
author = {Saied Ghadimi and Pourayoubi, Mehrdad and Ali Asghar Ebrahimi Valmoozi},
title = {Synthesis and Spectroscopic Characterization of Mixed Diamidophosphoric Acid Esters: X-Ray Crystal Structure of [(CH3)2N]-[p-H3C-C6H4-O]P(O)X (X = NHC(CH3)3 and p-H3C-C6H4-NH)},
journal = {Zeitschrift fur Naturforschung B: Chemical Sciences},
year = {2009},
volume = {64},
number = {5},
month = {May},
issn = {0932-0776},
pages = {565--569},
numpages = {4},
keywords = {Mixed Diamidophosphoric Acid Ester; Spectroscopic Characterization; X-Ray Crystal
Structure},
}
%0 Journal Article
%T Synthesis and Spectroscopic Characterization of Mixed Diamidophosphoric Acid Esters: X-Ray Crystal Structure of [(CH3)2N]-[p-H3C-C6H4-O]P(O)X (X = NHC(CH3)3 and p-H3C-C6H4-NH)
%A Saied Ghadimi
%A Pourayoubi, Mehrdad
%A Ali Asghar Ebrahimi Valmoozi
%J Zeitschrift fur Naturforschung B: Chemical Sciences
%@ 0932-0776
%D 2009
