Russian Journal of Inorganic Chemistry‎, ( ISI ), Volume (55), No (3), Year (2010-1) , Pages (355-360)

Title : ( Effect of Non-Aqueous Solvents on Stoichiometry and Selectivity of Complexes Formed Between 4 Nitrobenzo 15 Crown 5 with Fe3+, Y3+, Cd2+, Sn4+, Ce3+ and Au3+ Metal Cations )

Authors: Glamhossein Ronagi , Mohammad Hassan Soorgy , ,

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Abstract

The complexation processes between Fe3+, Y3+, Cd2+, Sn4+, Ce3+ and Au3+ metal cations with macrocyclic ligand, 4 _nitrobenzo_15_crown_5(4 NB15C5), were studied in acetonitrile (AN), methanol (MeOH) and nitromethane (NM) solvents at different temperatures using conductometric method. The conductance data show that the stoichiometry of the complexes formed between this macrocyclic ligand and Cd2+, Au3+ cations is 1:1 (ML), but in the case of Fe3+, Y3+ and Ce3+ metal cations, 2: 1 (M2 : L) and 2: 2 [M2 : L2] complexes are formed in nitromethane solutions. The results show, that the selectivity of 4 NB15C5 for the studied metal cations in methanol solutions at 15°C is: Sn4+ > Cd2+ > Y3+ > Fe3+ ≈ Ce3+ > Au3+, but in the case of acetonitrile, the stability order was found to be: Y3+ > Au3+ > Fe3+ > Cd2+. The values of stability constants of the 1:1 [M:L] complexes were determined from conductometric data using a GENPLOT computer program. The values of thermodynamic parameter ( and ) for formation of the complexes were obtained from temperature dependence of the stability constants, using the van’t Hoff plots. The results show that the values of standard enthalpy ( ) and standard entropy ( ) change with the nature of the non aqueous solvents.

Keywords

, 4 nitrobenzo 15 crown 5, Fe3+, Y3+, Cd2+, Sn4+, Ce3+ and Au3+ cations, Acetonitrile, Metha nol, Nitromethane, Conductometry.
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@article{paperid:1013820,
author = {Ronagi, Glamhossein and Soorgy, Mohammad Hassan and , },
title = {Effect of Non-Aqueous Solvents on Stoichiometry and Selectivity of Complexes Formed Between 4 Nitrobenzo 15 Crown 5 with Fe3+, Y3+, Cd2+, Sn4+, Ce3+ and Au3+ Metal Cations},
journal = {Russian Journal of Inorganic Chemistry‎},
year = {2010},
volume = {55},
number = {3},
month = {January},
issn = {0036-0236},
pages = {355--360},
numpages = {5},
keywords = {4 nitrobenzo 15 crown 5; Fe3+; Y3+; Cd2+; Sn4+; Ce3+ and Au3+ cations; Acetonitrile; Metha nol; Nitromethane; Conductometry.},
}

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%0 Journal Article
%T Effect of Non-Aqueous Solvents on Stoichiometry and Selectivity of Complexes Formed Between 4 Nitrobenzo 15 Crown 5 with Fe3+, Y3+, Cd2+, Sn4+, Ce3+ and Au3+ Metal Cations
%A Ronagi, Glamhossein
%A Soorgy, Mohammad Hassan
%A ,
%J Russian Journal of Inorganic Chemistry‎
%@ 0036-0236
%D 2010

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