European Journal of Chemistry, Volume (1), No (3), Year (2010-9) , Pages (179-181)

Title : ( A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure )

Authors: Hossein Eshtiagh Hosseini , milad mahjoobizadeh , Masoud Mirzaei Shahrabi , Katharina Frommb , Katharina M. Fromm , Aurelien Crochet ,

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A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6‐triamino‐1,3,5‐triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X‐ray structure determination. The crystal structure of the title compound consists of bis‐ 2,4,6‐triamino‐1,3,5‐triazin‐1‐ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O−H•••O, N−H•••O, and N−H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π−π stacking (centroid‐centroid ranges 3.410‐3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network.

Keywords

, Proton transfer compound X‐ray crystal structure 2, 4, 6‐Triamino‐1, 3, 5‐triazine Citric acid π−π
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@article{paperid:1017495,
author = {Eshtiagh Hosseini, Hossein and Mahjoobizadeh, Milad and Mirzaei Shahrabi, Masoud and Katharina Frommb and Katharina M. Fromm and Aurelien Crochet},
title = {A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure},
journal = {European Journal of Chemistry},
year = {2010},
volume = {1},
number = {3},
month = {September},
issn = {2153-2249},
pages = {179--181},
numpages = {2},
keywords = {Proton transfer compound X‐ray crystal structure 2;4;6‐Triamino‐1;3;5‐triazine Citric acid π−π Stacking},
}

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%0 Journal Article
%T A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure
%A Eshtiagh Hosseini, Hossein
%A Mahjoobizadeh, Milad
%A Mirzaei Shahrabi, Masoud
%A Katharina Frommb
%A Katharina M. Fromm
%A Aurelien Crochet
%J European Journal of Chemistry
%@ 2153-2249
%D 2010

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