Title : ( LIQUID PHASE ALKYLATION OF BENZENE WITH 1-DECENE OVER SILICA SUPPORTED H14[NaP5W30O110] AS A GREEN AND REUSABLE CATALYST )
Authors: Ali Ahmadpour , Ali Hafizi , MAJID M. HERAVI , FATEMEH F. BAMOHARRAM ,
Full TextAbstract
Alkylation of benzene with 1-decene was investigated for the production of linear alkylbenzene (LAB), using silica supported and bulk preyssler and keggin type heteropoly acids. Silica supported H14[NaP5W30O110] and H3PW12O40 catalysts with 40% loading were calcinated at 240 and 300°C, respectively. It is found that the catalysts exhibit much higher catalytic activity than conventional HF acid. At the reaction temperature of 80˚C, 2hr reaction time and atmospheric pressure of 40% H14[NaP5W30O110]/Sio2 showed the highest conversion (84%) and good selectivity (59%) to 2-phenyl decane.
Keywords
Linear alkylbenzene; Heteropoly acid; Preyssler; Alkylation; Green catalyst.
@inproceedings{paperid:1018037,
author = {Ahmadpour, Ali and Hafizi, Ali and MAJID M. HERAVI and FATEMEH F. BAMOHARRAM},
title = {LIQUID PHASE ALKYLATION OF BENZENE WITH 1-DECENE OVER SILICA SUPPORTED H14[NaP5W30O110] AS A GREEN AND REUSABLE CATALYST},
booktitle = {INTERNATIONAL CONFERENCE ON ENVIRONMENT 2010},
year = {2010},
location = {پینانگ},
keywords = {Linear alkylbenzene; Heteropoly acid; Preyssler; Alkylation; Green catalyst.},
}
%0 Conference Proceedings
%T LIQUID PHASE ALKYLATION OF BENZENE WITH 1-DECENE OVER SILICA SUPPORTED H14[NaP5W30O110] AS A GREEN AND REUSABLE CATALYST
%A Ahmadpour, Ali
%A Hafizi, Ali
%A MAJID M. HERAVI
%A FATEMEH F. BAMOHARRAM
%J INTERNATIONAL CONFERENCE ON ENVIRONMENT 2010
%D 2010
