Title : ( The preparation, spectroscopic characterization and X-ray crystal structures of the pyrrole-2-carboxaldehyde Schiff base of S-allyldithiocarbazate (HL) and its nickel(II) complex ([Ni(L)2]) )
Authors: Mohammad Yazdanbakhsh , Reza Takjoo , walter Frank , Amir Aghaei Kaju ,
Full TextAbstract
A new bidentate Schiff base (HL) derived from the condensation of S-allyldithiocarbazate with pyrrole-2-carboxaldehyde and its complex NiL2 have been prepared and characterized by elemental analyses, IR, NMR, UV-Vis spectroscopy, mass spectrometry, and molar conductivity measurements. The structures of ligand and NiL2 complex have been determined using X-ray diffraction analysis. Ligand and Ni(II) complex crystallize in the tetragonal space group P42/n with the unit cell parameters a=22.1827(18)A˚, c=4.5388(3)A˚ , V=2233.4(3)A˚3, Z=8 and in the monoclinic space group P21/c with the unit cell parameters a¼9.9998(14)A˚ , b=15.1322(16)A˚ , c=7.5920(11)A˚, B=99.397(17)˚, V=1133.4(3)A˚3, and Z=2, respectively. X-ray crystallographic structural analysis confirms that two Schiff bases of S-allyldithiocarbazate is coordinated to nickel as a uninegatively charged bidentate NS chelating agent via the azomethine nitrogen and the thiolate sulfur. NiL2 is square planar with cis-configuration.
Keywords
, Nickel complex; S, allyldithiocarbazate; Bidentate NS Schiff bases; Crystal structure
@article{paperid:1021841,
author = {Yazdanbakhsh, Mohammad and Takjoo, Reza and Walter Frank and Amir Aghaei Kaju},
title = {The preparation, spectroscopic characterization and X-ray crystal structures of the pyrrole-2-carboxaldehyde Schiff base of S-allyldithiocarbazate (HL) and its nickel(II) complex ([Ni(L)2])},
journal = {Journal of Coordination Chemistry},
year = {2009},
volume = {62},
number = {22},
month = {July},
issn = {0095-8972},
pages = {3651--3660},
numpages = {9},
keywords = {Nickel complex; S-allyldithiocarbazate; Bidentate NS Schiff bases; Crystal structure},
}
%0 Journal Article
%T The preparation, spectroscopic characterization and X-ray crystal structures of the pyrrole-2-carboxaldehyde Schiff base of S-allyldithiocarbazate (HL) and its nickel(II) complex ([Ni(L)2])
%A Yazdanbakhsh, Mohammad
%A Takjoo, Reza
%A Walter Frank
%A Amir Aghaei Kaju
%J Journal of Coordination Chemistry
%@ 0095-8972
%D 2009
