Title : ( Mixed Ligand Palladium(II) Complex with NS-Bidentate S-Allyldithiocarbazate Schiff Base: Synthesis, Spectral Characterization, Crystal Structure and Decoding Intermolecular Interactions with Hirshfeld Surface Analysis )
Authors: Reza Takjoo , Rozita Takjoo , Mohammad Yazdanbakhsh , Amir Aghaei kaju , Yaguang Chen ,
Full TextAbstract
A new mixed ligand palladium(II) complex with bidentate NS-donor chelate, [PdCl(PPh3)L] (L: S-allyl β-N-(benzylidene)dithiocarbazate), has been prepared and characterized using single crystal X-ray diffraction and spectroscopic (electronic, IR, 1H NMR and 13C NMR) techniques. The shorter Pd—P bond distance, 2.255(7) Å, than the sum of the single bond radii for palladium and phosphorus (2.41 Å), showed partial double bond character. Visualizing and exploring the crystal structure using Hirshfeld surface analysis showed the presence of π…π, N…π, C—H…π, Cl…H and weak C—H…S interactions as most important intermolecular interactions in the crystal lattice, which are responsible to extension of the supramolecular network of the compound and stabilization of the crystal structure.
Keywords
, palladium(II), S-allyldithiocarbazate, X-ray crystal structure, Hirshfeld surface analysis
@article{paperid:1021844,
author = {Takjoo, Reza and Rozita Takjoo and Yazdanbakhsh, Mohammad and Amir Aghaei Kaju and Yaguang Chen},
title = {Mixed Ligand Palladium(II) Complex with NS-Bidentate S-Allyldithiocarbazate Schiff Base: Synthesis, Spectral Characterization, Crystal Structure and Decoding Intermolecular Interactions with Hirshfeld Surface Analysis},
journal = {Chinese Journal of Chemistry},
year = {2010},
volume = {28},
number = {2},
month = {February},
issn = {1001-604X},
pages = {221--228},
numpages = {7},
keywords = {palladium(II); S-allyldithiocarbazate; X-ray crystal structure; Hirshfeld surface analysis},
}
%0 Journal Article
%T Mixed Ligand Palladium(II) Complex with NS-Bidentate S-Allyldithiocarbazate Schiff Base: Synthesis, Spectral Characterization, Crystal Structure and Decoding Intermolecular Interactions with Hirshfeld Surface Analysis
%A Takjoo, Reza
%A Rozita Takjoo
%A Yazdanbakhsh, Mohammad
%A Amir Aghaei Kaju
%A Yaguang Chen
%J Chinese Journal of Chemistry
%@ 1001-604X
%D 2010
