12th Iranian Inorganic Chemistry Conference , 2010-09-15

Title : ( Synthesis and Characterization of Two Organic-Inorganic Hybrids Obtained fromReaction of Keggin-typ Polyoxometallates with 2-Amino-4-methyl pyridine and 2-Aminopyrimidine Spacers )

Authors: Shima Edalatkar Moghadama , Hossein Eshtiagh Hosseini , Masoud Mirzaei Shahrabi ,

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Polyoxometallate constitute a fascinating class of metal-oxygen cluster-compounds with definite size and shape. They have been found to be extremely versatile inorganic building blocks in view of their potential applications in catalysis, medicine, theoretical studies, and materials science. Herein, two new organic-inorganic hybrids Materials based on Polyoxometallate, have been successfully synthesized and characterized by elemental analyses, IR, NMR spectroscopies. According to the obtained results these two hydrated hybrids may be formulated as (2- aminopyrimidinium)4(SiO4W12O36) and (2-amino,4-methyl pyridinium)3(PO4W12O36). In these cases, Keggin anions act as electron accepting species which leading to unique features for synthesized hybrids.

Keywords

, Polyoxometallates;Organic-inorganic hybrid material;2-Amino, 4-methyl
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@inproceedings{paperid:1022267,
author = {Shima Edalatkar Moghadama and Eshtiagh Hosseini, Hossein and Mirzaei Shahrabi, Masoud},
title = {Synthesis and Characterization of Two Organic-Inorganic Hybrids Obtained fromReaction of Keggin-typ Polyoxometallates with 2-Amino-4-methyl pyridine and 2-Aminopyrimidine Spacers},
booktitle = {12th Iranian Inorganic Chemistry Conference},
year = {2010},
location = {گیلان, IRAN},
keywords = {Polyoxometallates;Organic-inorganic hybrid material;2-Amino;4-methyl pyridine;2- Aminopyrimidine},
}

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%0 Conference Proceedings
%T Synthesis and Characterization of Two Organic-Inorganic Hybrids Obtained fromReaction of Keggin-typ Polyoxometallates with 2-Amino-4-methyl pyridine and 2-Aminopyrimidine Spacers
%A Shima Edalatkar Moghadama
%A Eshtiagh Hosseini, Hossein
%A Mirzaei Shahrabi, Masoud
%J 12th Iranian Inorganic Chemistry Conference
%D 2010

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