Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, ( ISI ), Volume (41), Year (2011-1) , Pages (1-8)

Title : ( Preyssler Heteropolyacid Supported on Nano-SiO2: A Green and Reusable Catalyst in Selective Oxidation of Benzyl Alcohols to Benzaldehydes )

Authors: F. Bamoharram , M. Heravi , H. Teymouri , Seyed Mojtaba Zebarjad , Ali Ahmadpour ,

Citation: BibTeX | EndNote

An efficient, improved, and environmentally benign procedure for catalytic oxidation of benzyl alcohols to the corresponding ben zaldehdes was developed in the presence of nano-SiO2-supported Preyssler heteropolyacid (HPA), both in thermal conditions and under microwave irradiation. Silica nanostructures were obtained through a sol–gel method and were characterized by transmission electron microscopy and powder x-ray diffraction. Nano-SiO2- supported Preyssler HPA was synthesized by an impregnation method and confirmed by infrared spectroscopy. In catalytic reactions, the effects of various parameters such as catalyst loading, catalyst amount, temperature, and reaction time were studied and the optimum conditions were obtained.

Keywords

, benzyl alcohols, catalyst, heteropolyacid, nano-SiO2- supported,
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@article{paperid:1023977,
author = {F. Bamoharram and M. Heravi and H. Teymouri and Zebarjad, Seyed Mojtaba and Ahmadpour, Ali},
title = {Preyssler Heteropolyacid Supported on Nano-SiO2: A Green and Reusable Catalyst in Selective Oxidation of Benzyl Alcohols to Benzaldehydes},
journal = {Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry},
year = {2011},
volume = {41},
month = {January},
issn = {1553-3174},
pages = {1--8},
numpages = {7},
keywords = {benzyl alcohols; catalyst; heteropolyacid; nano-SiO2- supported; Preyssler},
}

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%0 Journal Article
%T Preyssler Heteropolyacid Supported on Nano-SiO2: A Green and Reusable Catalyst in Selective Oxidation of Benzyl Alcohols to Benzaldehydes
%A F. Bamoharram
%A M. Heravi
%A H. Teymouri
%A Zebarjad, Seyed Mojtaba
%A Ahmadpour, Ali
%J Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
%@ 1553-3174
%D 2011

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