Title : ( [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-kN]hydrazin-1-ylidene-kN1}ethyl)-phenolato-kO](dimethylsulfoxide-kO)-dioxidomolybdenum(VI) )
Authors: Reza Takjoo , S. Weng Ng , E. R. T.Tiekink ,
Full TextAbstract
The MoVI atom in the title complex, [Mo(C11H13N3OS)O2-(C2H6OS)], is N,N0,O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octahedral N2O4 donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N—H O hydrogen bonds and eight-membered { HNMoO}2 loops. The Schiff base ligand is disordered over two orientations of equal occupancy.
Keywords
, [2, (1, {2, [Azanidyl(ethylsulfanyl)methylidene, kN]hydrazin, 1, ylidene, kN1}ethyl), phenolato,
@article{paperid:1029246,
author = {Takjoo, Reza and S. Weng Ng and E. R. T.Tiekink},
title = {[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-kN]hydrazin-1-ylidene-kN1}ethyl)-phenolato-kO](dimethylsulfoxide-kO)-dioxidomolybdenum(VI)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
month = {June},
issn = {1600-5368},
pages = {944--945},
numpages = {1},
keywords = {[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-kN]hydrazin-1-ylidene-kN1}ethyl)-phenolato-},
}
%0 Journal Article
%T [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-kN]hydrazin-1-ylidene-kN1}ethyl)-phenolato-kO](dimethylsulfoxide-kO)-dioxidomolybdenum(VI)
%A Takjoo, Reza
%A S. Weng Ng
%A E. R. T.Tiekink
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
