Acta Crystallographica Section E: Structure Reports Online, ( ISI ), Volume (68), Year (2012-8) , Pages (1033-1034)

Title : ( Oxido[2-{(E)-[((1E)-{(E)-2-[1-(2-oxidophenyl)ethylidene]hydrazin-1-ylidene}-(prop-2-en-1-ylsulfanyl)methyl)imino]-methyl}phenolato]vanadium(IV) )

Authors: Reza Takjoo , S. Weng Ng , E. R. T. Tiekink ,

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The VIV atom in the title complex, [V(C19H17N3O2S)O], is coordinated by two N and two O atoms of the dianionic tetradentate Schiff base ligand and the terminal oxide O atom. The N2O3 donor set defines a square-pyramidal coordination geometry with the oxide O atom in the apical site. Some buckling in the tetradentate ligand is indicated by the dihedral angle of 17.92 (19)_ between the six-membered chelate rings. Supramolecular chains are formed along the b axis via C—H_ _ _O contacts in the crystal. The chains are connected into a layer in the ab plane via C—H_ _ __ interactions. The atoms comprising the –SCH2—CH CH2 and methyl substituents were found to be disordered in a 0.916 (2):0.088 (2) ratio. The crystal studied was found to be twinned by nonmerohedry with a 28.1 (4)% minor twin component.


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author = {Takjoo, Reza and S. Weng Ng and E. R. T. Tiekink},
title = {Oxido[2-{(E)-[((1E)-{(E)-2-[1-(2-oxidophenyl)ethylidene]hydrazin-1-ylidene}-(prop-2-en-1-ylsulfanyl)methyl)imino]-methyl}phenolato]vanadium(IV)},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
month = {August},
issn = {1600-5368},
pages = {1033--1034},
numpages = {1},
keywords = {Oxido[2-{(E)-[((1E)-{(E)-2-[1-(2-oxidophenyl)ethylidene]hydrazin-1-ylidene}-(prop-2-en-1-ylsulfanyl)},


%0 Journal Article
%T Oxido[2-{(E)-[((1E)-{(E)-2-[1-(2-oxidophenyl)ethylidene]hydrazin-1-ylidene}-(prop-2-en-1-ylsulfanyl)methyl)imino]-methyl}phenolato]vanadium(IV)
%A Takjoo, Reza
%A S. Weng Ng
%A E. R. T. Tiekink
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012