Title : ( Conformation, Structure, Intramolecular H-bonding, and Vibrational Assignment of 1-(2-thienyl)-4,4,4-trifluorobutane-1,3-dione )
Authors: Mohamad Vakili ,
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Abstract
All four chelated forms of TTFA coexist in the solid and solution states. The negative and positive effects for trifluoromethyl and thienyl groups, respectively, in position on the IHB strength of the -dicarbonyls are concluded. In agreement with the theoretical stability calculations and X-ray experimental investigation, the vibrational spectroscopy analysis specify a more ratio of A forms in the solution phases, and a more ratio of B forms in the solid state in the sample.
Keywords
, 1-(2-thienyl)-4, 4, 4-trifluorobutane-1, 3-dione
@inproceedings{paperid:1038223,
author = {Vakili, Mohamad},
title = {Conformation, Structure, Intramolecular H-bonding, and Vibrational Assignment of 1-(2-thienyl)-4,4,4-trifluorobutane-1,3-dione},
booktitle = {13th Iranian Physical Chemistry Conference},
year = {2010},
location = {شیراز, IRAN},
keywords = {1-(2-thienyl)-4;4;4-trifluorobutane-1;3-dione},
}
%0 Conference Proceedings
%T Conformation, Structure, Intramolecular H-bonding, and Vibrational Assignment of 1-(2-thienyl)-4,4,4-trifluorobutane-1,3-dione
%A Vakili, Mohamad
%J 13th Iranian Physical Chemistry Conference
%D 2010
