Journal of Chemical Sciences, ( ISI ), Volume (126), No (6), Year (2014-6) , Pages (1903-1912)

Title : ( Fe(HSO4)3: An efficient, heterogeneous and reusable catalyst for C-alkylation of β-dicar bonyl compounds )

Authors: , Batool Akhlaghinia , , Hossein Eshghi ,

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Fe(HSO4)3(FHS) was used as an efficient catalyst for the heterogeneous addition of a series of benzylic and allylic alcohols to various β-dicarbonyl compounds, which afforded moderate to excellent yields of C-alkylated products in 1,2-dichloroethane. In comparison with the previous methods, the present research surprisingly exhibited higher reaction yields without formation of any by-products which could be formed by self-condensation of alcohols. Moreover, the catalyst can be readily recovered and reused up to five times with almost maintained reactivity and yields

Keywords

, β, Dicarbonyl compounds; ferric hydrogen sulphate Fe(HSO4)3; C, alkylation;
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@article{paperid:1045486,
author = {, and Akhlaghinia, Batool and , and Eshghi, Hossein},
title = {Fe(HSO4)3: An efficient, heterogeneous and reusable catalyst for C-alkylation of β-dicar bonyl compounds},
journal = {Journal of Chemical Sciences},
year = {2014},
volume = {126},
number = {6},
month = {June},
issn = {0974-3626},
pages = {1903--1912},
numpages = {9},
keywords = {β-Dicarbonyl compounds; ferric hydrogen sulphate Fe(HSO4)3; C-alkylation; heterogeneous catalyst.},
}

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%0 Journal Article
%T Fe(HSO4)3: An efficient, heterogeneous and reusable catalyst for C-alkylation of β-dicar bonyl compounds
%A ,
%A Akhlaghinia, Batool
%A ,
%A Eshghi, Hossein
%J Journal of Chemical Sciences
%@ 0974-3626
%D 2014

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