Title : ( Effect of Halocarbon as Promoter on Activity of Ziegler-Natta Catalyst in 1-Hexene Polymerization )
Authors: maliheh mazaherian , Ali Dashti , Mohamad Mahdi Mortazavi , Saied Ahmadjo ,
Full TextAbstract
The effect of halocarbon on catalyst activity of 1-hexene polymerization uisng Ziegler-Natta catalyst was investigated. At first, effect of temperature, co-catalyst concentration and monomer concentration was investigated to obtain optimal reaction conditions and maximum catalyst activity. Then, chlorocyclohexane was added in reaction medium and polymerization was carried out using 30ml of 1-hexene and 1.5 ml of Triisobutylaluminum (TIBA) as co-catalyst at Room temperature. It was found that the presence of halocarbon has a crucial role on the catalyst activity when compared to when no promoter was used. In addition, by incresing halocarbon to 2 ml ,the activity incresed and it has a descending trend thereafter.
Keywords
, Promotor, Polymerization, 1-Hexene, Ziegler-Natta catalyst
@inproceedings{paperid:1053520,
author = {Mazaherian, Maliheh and Dashti, Ali and Mohamad Mahdi Mortazavi and Saied Ahmadjo},
title = {Effect of Halocarbon as Promoter on Activity of Ziegler-Natta Catalyst in 1-Hexene Polymerization},
booktitle = {The 9 th International Chemical Engineering Congress & Exhibition (IChEC 2015)},
year = {2015},
location = {شیراز, IRAN},
keywords = {Promotor; Polymerization; 1-Hexene; Ziegler-Natta catalyst},
}
%0 Conference Proceedings
%T Effect of Halocarbon as Promoter on Activity of Ziegler-Natta Catalyst in 1-Hexene Polymerization
%A Mazaherian, Maliheh
%A Dashti, Ali
%A Mohamad Mahdi Mortazavi
%A Saied Ahmadjo
%J The 9 th International Chemical Engineering Congress & Exhibition (IChEC 2015)
%D 2015
