Title : ( Synthesis, Spectroscopic Study and Crystal Structure of a New Amidophosphonate, (C6H5O)2P(O)(NHCH(CH3)(C2H5)) )
Authors: Farahnaz Hamzehee Harzanji , Mehrdad Pourayoubi , Duane CHOQUESILLO LAZARTE ,
Full TextAbstract
The crystal structure of diphenyl (2-butylamido) phosphonate has been determined. This crystal belongs to the space group P21/c, and the asymmetric unit of the structure is composed of one complete molecule. The P atom has a distorted tetrahedral configuration with the O—P—O angle as the minimum bond angle at the P atom (97.74(18)°) and one of the O═P—O angles as the maximum angle (115.2(2)°). The oxygen atom of the P—O—C6H5 moiety may be ascribed with sp2 character, reflected in the P—O—C angles (120.8(3)° and 125.4(3)°). In the crystal structure, the molecules are aggregated through the N—H…O═P hydrogen bond (N1…O1 = 2.971(5)Å) in a one-dimensional chain along the b axis.
Keywords
, Crystal Structure, Amidophosphonate, Spectroscopic Study
@article{paperid:1058714,
author = {Hamzehee Harzanji, Farahnaz and Pourayoubi, Mehrdad and Duane CHOQUESILLO LAZARTE},
title = {Synthesis, Spectroscopic Study and Crystal Structure of a New Amidophosphonate, (C6H5O)2P(O)(NHCH(CH3)(C2H5))},
journal = {X-ray Structure Analysis Online},
year = {2016},
volume = {32},
number = {10},
month = {October},
issn = {1883-3578},
pages = {47--48},
numpages = {1},
keywords = {Crystal Structure; Amidophosphonate; Spectroscopic Study},
}
%0 Journal Article
%T Synthesis, Spectroscopic Study and Crystal Structure of a New Amidophosphonate, (C6H5O)2P(O)(NHCH(CH3)(C2H5))
%A Hamzehee Harzanji, Farahnaz
%A Pourayoubi, Mehrdad
%A Duane CHOQUESILLO LAZARTE
%J X-ray Structure Analysis Online
%@ 1883-3578
%D 2016
