Title : ( A redetermination of the crystal structure of the mannitol complex NH4[Mo2O5(C6H11O6)]·H2O: hydrogen-bonding scheme and Hirshfeld surface analysis )
Authors: Masoud Mirzaei Shahrabi , mortaza tahmasebi heydarabad , Joel T. Mague ,
Full TextAbstract
The redetermined structure [for the previous study, see: Godfrey & Waters (1975). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-trihydroxyhexane-2,3,4-tris(olato)]bis[dioxidomolybdenum(V)] monohydrate, NH4[Mo2(C6H11O6)O5]·H2O, was obtained from an attempt to prepare a glutamic acid complex from the [Co2Mo10H4O38]6− anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N—H...O, O—H...O and C—H...O hydrogen bonds. A Hirshfeld surface analysis was also performed.
Keywords
crystal structure; mannitol; molybdenum complex; hydrogen bond.
@article{paperid:1079235,
author = {Mirzaei Shahrabi, Masoud and Tahmasebi Heydarabad, Mortaza and جول ت. مگ},
title = {A redetermination of the crystal structure of the mannitol complex NH4[Mo2O5(C6H11O6)]·H2O: hydrogen-bonding scheme and Hirshfeld surface analysis},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2020},
volume = {76},
number = {4},
month = {April},
issn = {2056-9890},
pages = {518--522},
numpages = {4},
keywords = {crystal structure; mannitol; molybdenum complex; hydrogen bond.},
}
%0 Journal Article
%T A redetermination of the crystal structure of the mannitol complex NH4[Mo2O5(C6H11O6)]·H2O: hydrogen-bonding scheme and Hirshfeld surface analysis
%A Mirzaei Shahrabi, Masoud
%A Tahmasebi Heydarabad, Mortaza
%A جول ت. مگ
%J Acta Crystallographica Section E: Crystallographic Communications
%@ 2056-9890
%D 2020
