Title : ( Metals recovery from hydrodesulfurization catalysts: a profitability analysis )
Authors: Hossein Shalchian ,Access to full-text not allowed by authors
Abstract
The paper aims to present a techno-economic analysis to recover nickel, molybdenum, and vanadium from spent hydrodesulfurization (HDS) catalysts. Some of these catalysts are wet because of residual naphtha or other hydrocarbon fractions, in a 5-13% concentration range. Others, instead, are dried and dusty, mainly containing coke and sulfur. Some are based on active metals like Ni-Mo, others on Co-Mo. The plant, with a 6000 tons/year capacity, is based on a industrial process with pre-treatment thermal stages tested on a pilot scale. In contrast, the hydrometallurgical section was studied at the University of L\\\'Aquila. The simulations were carried out using lab- and pilot-scale experimental data. Only wet Ni-Mo catalyst was used as the plant\\\'s feedstock, producing 1272 tons/year of V2O5 98%wt, 239 tons/year of MoO3 57%wt, and 227 tons/year of Ni-V-Mo alloy with an approximate composition of 72-25-3%wt, respectively. The investment is highly profitable, with a net profit of around 14.1 MEUR/year, gross margin of 37.2%, return on investment equal to 23.9%, and a payback time slightly greater than 4 years.
Keywords
Catalyst; Hydrodesulfurization; Molybdenum; Nickel; Vanadium; Recycling; Oil@inproceedings{paperid:1092394,
author = {Shalchian, Hossein},
title = {Metals recovery from hydrodesulfurization catalysts: a profitability analysis},
booktitle = {(Cyprus) 17th Conference on Sustainable Development of Energy, Water and Environment Systems - SDEWES 2022. 6-10 November, 2022. Paphos},
year = {2022},
location = {Paphos},
keywords = {Catalyst; Hydrodesulfurization; Molybdenum; Nickel; Vanadium; Recycling; Oil},
}
%0 Conference Proceedings
%T Metals recovery from hydrodesulfurization catalysts: a profitability analysis
%A Shalchian, Hossein
%J (Cyprus) 17th Conference on Sustainable Development of Energy, Water and Environment Systems - SDEWES 2022. 6-10 November, 2022. Paphos
%D 2022