Journal of the Australian Ceramic Society, Volume (59), No (3), Year (2023-7) , Pages (795-809)

Title : ( Cu-Mn mixed-component oxide nanoparticles synthesized via the one-step solution combustion method with enhanced water evaporation efficiency )

Authors: , Sahar Mollazadeh Beidokhti , Mohammad Mustafa Ghafoorian ,

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Abstract

During the last few years, synthesis of mixed complex oxide components based on transition metal ions has attracted considerable scientifc attention. Accordingly, this work demonstrated the successful synthesis of multi-component oxides consisting of Cu2+ and Mn2+ as transition metal ions through the one-step solution combustion synthesis (SCS) process. The synthesized nanoparticles were characterized by an X-ray difractometer (XRD), feld emission scanning electron microscope (FESEM), difuse refectance spectroscopy (DRS), transition electron microscopy (TEM), and dynamic light scattering (DLS) analysis. XRD results revealed that multi-component oxides were crystallized during the combustion process. The FESEM results indicated that with increasing the ratio of Mn2+ to Cu2+, morphology changes from agglomerated nanorods and nanosheets to foam-like particles. Results of DLS analysis showed that the sample with the chemical composition containing an equal ratio of Mn2+ and Cu2+ had the lowest particle size distribution. In addition, the TEM micrograph demonstrated that the particle size distribution of the sample synthesized with two diferent multivalent cations (Mn2+ and Cu2+) was less than that of the sample synthesized with a single multivalent cation. Adsorption–desorption isotherms of the as-prepared powders showed the formation of porous particles with a specifc surface area of 168 m2 /g. DRS spectroscopy results implied that multicomponent samples had narrow bandgap energy of around 2.2 eV. Moreover, the solar-driven water evaporation mass results showed that the efciency of the water evaporation process in the presence of multi-component powders could reach 100%.

Keywords

Nanoparticle · Multivalent component · Solution combustion synthesis · Water evaporation
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@article{paperid:1096526,
author = {, and Mollazadeh Beidokhti, Sahar and محمد مصطفی غفوریان},
title = {Cu-Mn mixed-component oxide nanoparticles synthesized via the one-step solution combustion method with enhanced water evaporation efficiency},
journal = {Journal of the Australian Ceramic Society},
year = {2023},
volume = {59},
number = {3},
month = {July},
issn = {2510-1560},
pages = {795--809},
numpages = {14},
keywords = {Nanoparticle · Multivalent component · Solution combustion synthesis · Water evaporation},
}

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%0 Journal Article
%T Cu-Mn mixed-component oxide nanoparticles synthesized via the one-step solution combustion method with enhanced water evaporation efficiency
%A ,
%A Mollazadeh Beidokhti, Sahar
%A محمد مصطفی غفوریان
%J Journal of the Australian Ceramic Society
%@ 2510-1560
%D 2023

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