Title : ( Enhancing lithium-ion battery performance through novel spinel/layered heterostructured cathode design: a systematic investigation of xLi₄Mn₅O₁₂·(1-x)Li₁.₂Mn₀.₅Ni₀.₂Co₀.₁O₂ )
Authors: Amer Abdulabbas Sakran , Hadi Arabi , Shaban Reza Ghorbani , Nasrin Azad ,Access to full-text not allowed by authors
Abstract
This study presents the development and characterization of a novel spinel/layered heterostructured cathode material designed for enhanced energy storage capacity of lithium-ion batteries. The investigation began with the synthesis of Li-rich lay- ered (Li 1.2 Mn 0.5 Ni 0.2 Co 0.1 O 2 ) and spinel (Li 4 Mn 5 O 12) cathode materials via a modified sol–gel method. These materials were then integrated to create heterostructured cathodes with compositions of xLi 4 Mn 5 O 12 ·(1-x)Li 1.2 Mn 0.5 Ni 0.2 Co 0.1 O 2 (x = 0.01, 0.03, 0.05, and 0.07). Comprehensive structural characterization using X-ray diffraction (XRD), Raman spectros- copy, and high-resolution transmission electron microscopy (HR-TEM) confirmed the successful formation of the spinel/ layered heterostructure. X-ray photoelectron spectroscopy validated the presence of the Li 4 Mn 5 O 12 spinel structure within the heterostructure matrix and verified the valence states of transition metal ions. The electrochemical performance of the Li-rich layered and heterostructure cathode materials was assessed through various measurements, including galvanostatic charge–discharge at different C rates, cyclic voltammetry, differential capacity, and electrochemical impedance spectroscopy. Electrochemical performance evaluation revealed that the optimized composition (x = 0.01) exhibited superior performance metrics, delivering specific capacities of 299.38, 231.48, 205.03, 174.93, and 115.67 mAh g⁻1 at rates of 0.1C, 0.5C, 1C, 2C, and 5C, respectively. Notably, this composition maintained a stable capacity of 175.3 mAh g⁻1 after 100 cycles at 1C rate, representing a 76.89% capacity retention. The enhanced performance is attributed to the synergistic effect of the ultrathin spinel layer, which facilitates Li-ion diffusion kinetics while protecting the layered structure from electrolyte degradation.
Keywords
, Lithium, ion batteries · Heterostructured cathodes · Li, rich layered oxides · Spinel structure · Electrochemical performance · Surface modification@article{paperid:1104463,
author = {Sakran, Amer Abdulabbas and Arabi, Hadi and Ghorbani, Shaban Reza and نسرین آزاد},
title = {Enhancing lithium-ion battery performance through novel spinel/layered heterostructured cathode design: a systematic investigation of xLi₄Mn₅O₁₂·(1-x)Li₁.₂Mn₀.₅Ni₀.₂Co₀.₁O₂},
journal = {Ionics},
year = {2025},
volume = {31},
number = {8},
month = {August},
issn = {0947-7047},
pages = {7785--7802},
numpages = {17},
keywords = {Lithium-ion batteries · Heterostructured cathodes · Li-rich layered oxides · Spinel structure · Electrochemical
performance · Surface modification},
}
%0 Journal Article
%T Enhancing lithium-ion battery performance through novel spinel/layered heterostructured cathode design: a systematic investigation of xLi₄Mn₅O₁₂·(1-x)Li₁.₂Mn₀.₅Ni₀.₂Co₀.₁O₂
%A Sakran, Amer Abdulabbas
%A Arabi, Hadi
%A Ghorbani, Shaban Reza
%A نسرین آزاد
%J Ionics
%@ 0947-7047
%D 2025