Zeitschrift fur Anorganische und Allgemeine Chemie, ( ISI ), Year (2007-3)

Title : Synthesis, Characterization and Crystal Structure of Novel Mixed Bridged Trinuclear Oxo-Centered Iro ( Synthesis, characterization and crystal structure of novel mixed bridged trinuclear oxo-centered iron(III), chromium(III) complexes containing terminal unsaturated carboxylato and acrylic acid dimer anion ligands )

Authors: Mohammad Yazdanbakhsh , Mohammad Hasan Alizadeh Ghanad , خرم دل , Frank ,

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Abstract

Abstract. Three new oxo-centered trinuclear mixed-bridged carboxylate complexes with terminal unsaturated ligands ([M2M(μ3-O)(μ-O2C3H3)5(μ-O4C6H7)(O2C3H3) (H2O)2]·2H2O [M Fe, M  Fe (1); M  Fe, M  Cr (2); M  Cr, M  Fe (3)]) have been synthesized and characterized by means of elemental analyses, IR spectra and crystal structure analyses. The compounds crystallize isotypically in the orthorhombic space group type Pbcn with a  24.622(3)A ° , b  16.304(2)A ° , c  17.491(2)A ° , V  7021.5(15)A ° 3 (1), a  24.708(5)A ° , b  16.290(2)A ° , c 17.394(2)A ° , V  7001.0(18)A ° 3 (2), a  24.611(4)A ° , b  16.300(3)A ° , c  17.359(3)A ° , V  6964(2)A ° 3 (3), and Z  8. The infrared spectra show resolved bands arising from νasym(OCO) and νsym(OCO) vibrations of monodentate and bridging carboxylate ligands along with those of νasym(M2MO) vibrations in the complexes.

Keywords

Keywords: Carboxylate complexes; Trinuclear complexes; Oxocentered complexes; Crystal structure