Title : ( Synthesis and characterization of two novel mixed-valent and metal oxo-centered trinuclear complexes [Fe2CoO(CHCl2COO)6(py)3] and [Mn2MnO(CHCl2COO)6(py)3]. )
Authors: Mohammad Yazdanbakhsh , ,
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Abstract
Two novel m3-oxo trinuclear com plexes, [Fe2CoO(CHCl2COO)6(py)3] (1) and [Mn2MnO(CHCl2COO)6(py)3] (2) have been syn the sized and char ac ter ized by IR spec - tros copy, el e men tal anal y sis, UV-Vis spec tros copy and atomic absorption spec tros copy. Com plexes 1 and 2 are m3-oxo trinuclear com pounds with the three metal at oms bridged by six dichloroacetates groups. M3O and MO4 units adopted D3h and D4h lo - cal sym me try, re spec tively, and are sur rounded by six bridg ing dichloroacetates with C2u lo cal sym me try.
Keywords
, trinuclear complexes, bridging carboxylate, dichloroacetic acid, IR spectrum, UV-Vis spectrum
@article{paperid:1009441,
author = {Yazdanbakhsh, Mohammad and , },
title = {Synthesis and characterization of two novel mixed-valent and metal oxo-centered trinuclear complexes [Fe2CoO(CHCl2COO)6(py)3] and [Mn2MnO(CHCl2COO)6(py)3].},
journal = {Polish Journal of Chemistry},
year = {2008},
volume = {82},
month = {July},
issn = {0137-5083},
pages = {1519--1525},
numpages = {6},
keywords = {trinuclear complexes; bridging carboxylate; dichloroacetic acid; IR
spectrum; UV-Vis spectrum},
}
%0 Journal Article
%T Synthesis and characterization of two novel mixed-valent and metal oxo-centered trinuclear complexes [Fe2CoO(CHCl2COO)6(py)3] and [Mn2MnO(CHCl2COO)6(py)3].
%A Yazdanbakhsh, Mohammad
%A ,
%J Polish Journal of Chemistry
%@ 0137-5083
%D 2008
