Title : ( Synthesis and characterization of novel oxo-bridged, trinuclear mixed-metal complexes of Cr(III) and Fe(III) )
Authors: Mohammad Yazdanbakhsh , IMAN KHOSRAVI , ,
Full TextAbstract
Two new heterotrinuclear p-chlorobenzoates, [Fe2CrO(C7H4O2Cl)6(py)3]NO3 (1) and [Cr2FeO(C7H4O2Cl)6(py)3]NO3 (2) were prepared as nitrate salts and characterized by elemental analyses (CHN), spectroscopic (infrared, electronic) studies and atomic absorption spectroscopy. These complexes are a new type of oxo-bridged mixed-metal complex in which the carboxylate ligand is p-chlorobenzoic acid. Bridging coordination modes for the carboxylates were indicated by the presence of νasym (M2M’O) vibrations in the infrared spectra.
Keywords
, carboxylates; oxo, bridged complexes; p, chlorobenzoic acid; IR spectra.
@article{paperid:1022984,
author = {Yazdanbakhsh, Mohammad and KHOSRAVI, IMAN and , },
title = {Synthesis and characterization of novel oxo-bridged, trinuclear mixed-metal complexes of Cr(III) and Fe(III)},
journal = {Journal of the Serbian Chemical Society},
year = {2009},
volume = {74},
number = {4},
month = {April},
issn = {0352-5139},
pages = {401--406},
numpages = {5},
keywords = {carboxylates; oxo-bridged complexes; p-chlorobenzoic acid; IR spectra.},
}
%0 Journal Article
%T Synthesis and characterization of novel oxo-bridged, trinuclear mixed-metal complexes of Cr(III) and Fe(III)
%A Yazdanbakhsh, Mohammad
%A KHOSRAVI, IMAN
%A ,
%J Journal of the Serbian Chemical Society
%@ 0352-5139
%D 2009
